Organometallics

Current research reports and chronological list of recent articles.


The international scientific journal Organometallics records progress in one of the most active fields for organometallic, inorganic, organic, and materials chemists. Articles, communications, mini-reviews, and notes detail the synthesis, structure, bonding, chemical reactivity and reaction mechanisms, and applications of organometallic and organometalloidal compounds. Applications coverage includes organic and polymer synthesis, catalytic processes, and synthetic aspects of materials science and solid-state chemistry.

The publisher is the American Chemical Society, ACS. The copyright and publishing rights of specialized products listed below are in this publishing house. This is also responsible for the content shown.

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Additional research articles see Current Chemistry Research Articles. Magazines with similar content (organometallic chemistry):

 - Applied Organometallic Chemistry.

 - Dalton Transactions.

 - Journal of Inorganic and Organometallic Polymers and Materials.

 - Journal of Organometallic Chemistry.

 - Topics in Organometallic Chemistry.



Organometallics - Abstracts



Synergistic Mechanistic Study of Nickel(0)/Lewis Acid Catalyzed Cyanoesterification: Effect of Lewis Acid

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Organometallics
DOI: 10.1021/acs.organomet.7b00573

Datum: 22.11.2017


Quantifying Structural Effects of Amino Acid Ligands in Pd(II)-Catalyzed Enantioselective C–H Functionalization Reactions

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Organometallics
DOI: 10.1021/acs.organomet.7b00751

Datum: 21.11.2017


Direct Chlorination of Trispyrazolyl Borate Ligands in Tp-Ruthenium Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00546

Datum: 20.11.2017


Customizing Polyolefin Morphology by Selective Pairing of Alkali Ions with Nickel Phenoxyimine-Polyethylene Glycol Catalysts

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Organometallics
DOI: 10.1021/acs.organomet.7b00516

Datum: 17.11.2017


Rhodium Complexes of 2,6-Bis(dialkylphosphinomethyl)pyridines: Improved C–H Activation, Expanded Reaction Scope, and Catalytic Direct Arylation

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Organometallics
DOI: 10.1021/acs.organomet.7b00532

Datum: 16.11.2017


Synthesis of Base-Stabilized Hydrido(hydroborylene)tungsten Complexes and Their Reactions with Terminal Alkynes To Give η3-Boraallyl Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00723

Datum: 16.11.2017


C(sp2)–C(sp2) Reductive Elimination from Well-Defined Diarylgold(III) Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00588

Datum: 15.11.2017


Diastereoselective Synthesis of Planar Chiral Phosphoramidites with a Ferrocenophane Scaffold

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Organometallics
DOI: 10.1021/acs.organomet.7b00700

Datum: 15.11.2017


H–H and N–H Bond Cleavages of Dihydrogen and Ammonia by a Bifunctional Imido (NH)-Bridged Diiridium Complex: A DFT Study

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Organometallics
DOI: 10.1021/acs.organomet.7b00581

Datum: 15.11.2017


Counteranion-Controlled Ag2O-Mediated Benzimidazolium Ring Opening and Its Application in the Synthesis of Palladium Pincer-Type Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00651

Datum: 14.11.2017


Stereo- and Regioselective Addition of Arene to Alkyne Using Abnormal NHC Based Palladium Catalysts: Elucidating the Role of Trifluoroacetic Acid in Fujiwara Process

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Organometallics
DOI: 10.1021/acs.organomet.7b00649

Datum: 14.11.2017


Dicationic Thiolate-Bridged Diruthenium Complexes for Catalytic Oxidation of Molecular Dihydrogen

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Organometallics
DOI: 10.1021/acs.organomet.7b00764

Datum: 14.11.2017


Synthesis, Structures, and Redox Properties of Tetracyano-Bridged Diferrocene Donor–Acceptor–Donor Systems

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Organometallics
DOI: 10.1021/acs.organomet.7b00728

Datum: 14.11.2017


Synthesis and Reactivity of Model Intermediates Proposed for the Pd-Catalyzed Remote C–H Functionalization of N-(2-Haloaryl)acrylamides

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Organometallics
DOI: 10.1021/acs.organomet.7b00702

Datum: 14.11.2017


Evidence for Reversible Cyclometalation in Alkane Dehydrogenation and C–O Bond Cleavage at Iridium Bis(phosphine) Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00676

Datum: 13.11.2017


Ethylene Polymerization by Dinuclear Xanthene-Bridged Imino- and Aminopyridyl Nickel Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00698

Datum: 09.11.2017


Halide Control of N,N-Coordination versus N,C-Cyclometalation and Stereospecific Phenyl Ring Deuteration of Osmium(II) p-Cymene Phenylazobenzothiazole Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00501

Datum: 09.11.2017


Ferrocene-bis(phosphinimine) Nickel(II) and Palladium(II) Alkyl Complexes: Influence of the Fe–M (M = Ni and Pd) Interaction on Redox Activity and Olefin Coordination

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Organometallics
DOI: 10.1021/acs.organomet.7b00626

Datum: 08.11.2017


C–H Activation of π-Arene Ruthenium Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00563

Datum: 08.11.2017


An Extremely Electron Poor Cationic Triazoliumylidene N-Heterocyclic Carbene: Experimental and Computational Studies

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Organometallics
DOI: 10.1021/acs.organomet.7b00670

Datum: 07.11.2017


Influence of R–NHC Coupling on the Outcome of R–X Oxidative Addition to Pd/NHC Complexes (R = Me, Ph, Vinyl, Ethynyl)

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Organometallics
DOI: 10.1021/acs.organomet.7b00669

Datum: 07.11.2017


Mechanistic Studies of Redox-Switchable Copolymerization of Lactide and Cyclohexene Oxide by a Zirconium Complex

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Organometallics
DOI: 10.1021/acs.organomet.7b00672

Datum: 07.11.2017


Cobalt-Catalyzed Cross-Coupling Reactions of Arylboronic Esters and Aryl Halides

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Organometallics
DOI: 10.1021/acs.organomet.7b00726

Datum: 07.11.2017


Structural Characterization of Tridentate N-Heterocyclic Carbene Titanium(IV) Benzyloxide, Silyloxide, Acetate, and Azide Complexes and Assessment of Their Efficacies for Catalyzing the Copolymerization of Cyclohexene Oxide with CO2

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Organometallics
DOI: 10.1021/acs.organomet.7b00705

Datum: 07.11.2017


Distinctive Stereochemically Linked Cooperative Effects in Bimetallic Titanium Olefin Polymerization Catalysts

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Organometallics
DOI: 10.1021/acs.organomet.7b00641

Datum: 07.11.2017


Cp*RhIII-Catalyzed C–H Amidation of Ferrocenes

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Organometallics
DOI: 10.1021/acs.organomet.7b00691

Datum: 01.11.2017


Palladium-Catalyzed Reductive Cross-Coupling Reaction of Aryl Chromium(0) Fischer Carbene Complexes with Aryl Iodides

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Organometallics
DOI: 10.1021/acs.organomet.7b00657

Datum: 01.11.2017


Four- and Five-Coordinate Osmium(IV) Nitrides and Imides: Circumventing the “Nitrido Wall”

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Organometallics
DOI: 10.1021/acs.organomet.7b00707

Datum: 31.10.2017


Stabilization of Trans Disilyl Coordination at Square-Planar Platinum Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00566

Datum: 25.10.2017


Reductive Ring Opening of a Cyclo-Tri(phosphonio)methanide Dication to a Phosphanylcarbodiphosphorane: In Situ UV-Vis Spectroelectrochemistry and Gold Coordination

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Organometallics
DOI: 10.1021/acs.organomet.7b00597

Datum: 25.10.2017


Reductive Disproportionation of CO2 with Bulky Divalent Samarium Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00630

Datum: 20.10.2017


Cerium(III) Carbonate Formation from {CeCp*2H}2 and Carbon Dioxide: Structure and Mechanistic Insights

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Organometallics
DOI: 10.1021/acs.organomet.7b00639

Datum: 20.10.2017


Metal–Silicon Triple Bonds: Access to [Si(η5-C5Me5)]+ from SiX2(NHC) and its Conversion to the Silylidyne Complex [TpMe(CO)2MoSi(η3-C5Me5)] (TpMe = κ3-N,N′,N″-hydridotris(3,5-dimethyl-1-pyrazolyl)borate)

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Organometallics
DOI: 10.1021/acs.organomet.7b00665

Datum: 19.10.2017


Thorium(IV) and Uranium(IV) trans-Calix[2]benzene[2]pyrrolide Alkyl and Alkynyl Complexes: Synthesis, Reactivity, and Electronic Structure

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Organometallics
DOI: 10.1021/acs.organomet.7b00633

Datum: 16.10.2017


From Five to Five: Titanium Ketimine Complexes with Monoaza-butadiene η4-Coordination Mode and Hidden η2-Imine Reactivity

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Organometallics
DOI: 10.1021/acs.organomet.7b00673

Datum: 12.10.2017


Fluorenyl Half-Sandwich Bis(tetramethylaluminate) Complexes of the Rare-Earth Metals: Synthesis, Structure, and Isoprene Polymerization

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Organometallics
DOI: 10.1021/acs.organomet.7b00543

Datum: 11.10.2017


Experimental and Computational Studies of High-Valent Nickel and Palladium Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00613

Datum: 10.10.2017


Dinuclear Nickel Complexes of Thiolate-Functionalized Carbene Ligands and Their Electrochemical Properties

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Organometallics
DOI: 10.1021/acs.organomet.7b00576

Datum: 04.10.2017


A 1,2-Dicarbadodecaborane(12)-1,2-Dithiolate Chelating Ruthenium Carbene Catalyst for Highly Z Selective Olefin Metathesis

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Organometallics
DOI: 10.1021/acs.organomet.7b00556

Datum: 04.10.2017


Formation of a Uranium-Bound η1-Cyaphide (CP–) Ligand via Activation and C–O Bond Cleavage of Phosphaethynolate (OCP–)

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Organometallics
DOI: 10.1021/acs.organomet.7b00590

Datum: 03.10.2017


Elucidating Dramatic Ligand Effects on SET Processes: Iron Hydride versus Iron Borohydride Catalyzed Reductive Radical Cyclization of Unsaturated Organic Halides

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Organometallics
DOI: 10.1021/acs.organomet.7b00603

Datum: 27.09.2017


Reduction of Diphenylacetylene Mediated by Rare-Earth Ferrocene Diamide Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00541

Datum: 26.09.2017


From a (Pseudo) Aluminum Sesquihalide Al2(Et)3(ORF)3 to Me3Si–Cl–Al(ORF)3 (RF = C(CF3)3)

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Organometallics
DOI: 10.1021/acs.organomet.7b00557

Datum: 25.09.2017


Catalytic Addition of Alcohols to Carbodiimides Mediated by Benzimidazolin-2-iminato Actinide Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00432

Datum: 25.09.2017


Copper(I)–N-Heterocyclic Carbene Complexes as Efficient Catalysts for the Synthesis of 1,4-Disubstituted 1,2,3-Sulfonyltriazoles in Air

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Organometallics
DOI: 10.1021/acs.organomet.7b00506

Datum: 11.09.2017


B-Centered Reactivity of Persistent P-Stabilized Boryl Radicals

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Organometallics
DOI: 10.1021/acs.organomet.7b00598

Datum: 11.09.2017


Ligand Exchange on and Allylic C–H Activation by Iron(0) Fragments: π-Complexes, Allyliron Species, and Metallacycles

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Organometallics
DOI: 10.1021/acs.organomet.7b00571

Datum: 08.09.2017


Alkenyl-Assisted C3–C Bond Activation of Acetylacetonate Coordinated to Iridium

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Organometallics
DOI: 10.1021/acs.organomet.7b00523

Datum: 07.09.2017


Dual Redox and Optical Control of Chiroptical Activity in Photochromic Dithienylethenes Decorated with Hexahelicene and Bis-Ethynyl-Ruthenium Units

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Organometallics
DOI: 10.1021/acs.organomet.7b00534

Datum: 30.08.2017


Cationic Scandium Anisyl Species in Styrene Polymerization Using Anisole and N,N-Dimethyl-o-toluidine as Chain-Transfer Agents

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Organometallics
DOI: 10.1021/acs.organomet.7b00526

Datum: 30.08.2017


From a Piano Stool to a Sandwich: A Stepwise Route for Improving the Slow Magnetic Relaxation Properties of Thulium

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Organometallics
DOI: 10.1021/acs.organomet.7b00449

Datum: 29.08.2017


Investigations into the Photophysical and Electronic Properties of Pnictoles and Their Pnictenium Counterparts

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Organometallics
DOI: 10.1021/acs.organomet.7b00564

Datum: 29.08.2017


A Pd Halide Cluster from 1964: Pd6Cl8 Capped by Ring-Opened C3Ph3 Ligands from Oxidative Addition of Cyclopropenium Ions

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Organometallics
DOI: 10.1021/acs.organomet.7b00525

Datum: 28.08.2017


Experimental and Theoretical Mechanistic Investigation on the Catalytic CO2 Hydrogenation to Formate by a Carboxylate-Functionalized Bis(N-heterocyclic carbene) Zwitterionic Iridium(I) Compound

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Organometallics
DOI: 10.1021/acs.organomet.7b00509

Datum: 28.08.2017


Structural Characterization and Redox Activity of a Uranyl Dimer and Transition-Metal Complexes of a Tetradentate BIAN Ligand

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Organometallics
DOI: 10.1021/acs.organomet.7b00454

Datum: 24.08.2017


Reactivity of Scandium Terminal Imido Complex toward Boranes: C(sp3)–H Bond Borylation and B–O Bond Cleavage

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Organometallics
DOI: 10.1021/acs.organomet.7b00452

Datum: 16.08.2017


E–H (E = N and P) Bond Activation of PhEH2 by a Trinuclear Yttrium Methylidene Complex: Theoretical Insights into Mechanism and Multimetal Cooperation Behavior

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Organometallics
DOI: 10.1021/acs.organomet.7b00443

Datum: 16.08.2017


Isolation and Reactivity of a Digerma Analogue of Vinyllithiums: a Lithium Digermenide

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Organometallics
DOI: 10.1021/acs.organomet.7b00470

Datum: 03.08.2017


A [HN(BHNH)2]2– Dianion, Isoelectronic with a β-Diketiminate

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Organometallics
DOI: 10.1021/acs.organomet.7b00436

Datum: 02.08.2017


Synthesis and Reactions of [Cp*2Yb]2(μ-Me) and [Cp*2Yb]2(μ-Me)(Me) and Related Yb2(II, III) and Yb2(III, III) Compounds

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Organometallics
DOI: 10.1021/acs.organomet.7b00384

Datum: 01.08.2017


Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons

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Organometallics
DOI: 10.1021/acs.organomet.7b00385

Datum: 31.07.2017


Yttrium Methanide and Methanediide Bis(silyl)amide Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00394

Datum: 31.07.2017


Reversibility of Ketone Reduction by SmI2–Water and Formation of Organosamarium Intermediates

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Organometallics
DOI: 10.1021/acs.organomet.7b00392

Datum: 25.07.2017


Reductive Elimination of C6F5–C6F5 from Pd(II) Complexes: Influence of α-Dicationic Chelating Phosphines

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Organometallics
DOI: 10.1021/acs.organomet.7b00418

Datum: 25.07.2017


Rare Earth and Main Group Metal Poly(hydrosilyl) Compounds

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Organometallics
DOI: 10.1021/acs.organomet.7b00383

Datum: 24.07.2017


An N-Tethered Uranium(III) Arene Complex and the Synthesis of an Unsupported U–Fe Bond

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Organometallics
DOI: 10.1021/acs.organomet.7b00429

Datum: 20.07.2017


A Palladium(II) Complex of a C4 Chelating Bis(NHC) Diphosphonium Bis(ylide) Ligand

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Organometallics
DOI: 10.1021/acs.organomet.7b00405

Datum: 19.07.2017


Synthesis of Iron Hydride Complexes Relevant to Hydrogen Isotope Exchange in Pharmaceuticals

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Organometallics
DOI: 10.1021/acs.organomet.7b00398

Datum: 10.07.2017


Deprotonation of Group 14 Metal Amide Complexes Bearing Ditopic Carbanionic N-Heterocyclic Carbene Ligands. Constitutional Isomerism and Dynamic Behavior

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Organometallics
DOI: 10.1021/acs.organomet.7b00352

Datum: 29.06.2017


Cooperative Bond Activation Reactions with Ruthenium Carbene Complex PhSO2(Ph2PNSiMe3)CRu(p-cymene): RuC and N–Si Bond Reactivity

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Organometallics
DOI: 10.1021/acs.organomet.7b00254

Datum: 14.06.2017


Carbon Dioxide Activation by a Uranium(III) Complex Derived from a Chelating Bis(aryloxide) Ligand

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Organometallics
DOI: 10.1021/acs.organomet.7b00263

Datum: 31.05.2017


Acceptorless Alcohol Dehydrogenation: OH vs NH Effect in Bifunctional NHC–Ir(III) Complexes

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Organometallics
DOI: 10.1021/acs.organomet.7b00220

Datum: 18.05.2017


Reductive Elimination of Diphosphine from a Thorium–NHC–Bis(phosphido) Complex

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Organometallics
DOI: 10.1021/acs.organomet.7b00301

Datum: 11.05.2017


Reactivity of a Lewis Base Supported Thorium Terminal Imido Metallocene toward Small Organic Molecules

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Organometallics
DOI: 10.1021/acs.organomet.7b00212

Datum: 10.05.2017


Synthesis, Thermochemistry, Bonding, and 13C NMR Chemical Shift Analysis of a Phosphorano-Stabilized Carbene of Thorium

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Organometallics
DOI: 10.1021/acs.organomet.7b00202

Datum: 21.04.2017






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